欧盟提议修订玩具安全指令2009/48/EC中对致敏香料的要求
认证网 (2020/3/25 11:51:33) 浏览:424 评论:0
欧盟委员会起草了两项指令，以修订玩具安全指令2009/48/EC的附件II中对玩具中致敏香料的要求。以下为提议总结：
一、对须进行标签的致敏香料清单的修订
根据玩具安全指令2009/48/EC附件II第III部分的现行要求，第11点的第3段中表格所列致敏香料，若在玩具或其部件中添加的浓度超过100 mg/kg，则应在玩具、加贴标签、包装或随附单页上注明该致敏香料的名称。
欧盟委员会提议对此清单进行如下修订：
1.香茅醇（CAS号：106-22-9），增加2个CAS号（1117-61-9和7540-51-4）；
2.增加61种致敏香料，详见下表：
序号致敏香料名称CAS号
(12)Acetylcedrene
甲基柏木酮32388-55-9
(13)Amyl salicylate
水杨酸戊酯2050-08-0
(14)trans-Anethole
反式茴香脑4180-23-8
(15)Benzaldehyde
苯甲醛100-52-7
(16)Camphor
樟脑76-22-2; 464-49-3
(17)Carvone
香芹酮99-49-0; 6485-40-1;
2244-16-8
(18)beta-Caryophyllene (ox.)
β-石竹烯87-44-5
(19)Rose ketone-4 (Damascenone)
大马酮23696-85-7
(20)alpha-Damascone (TMCHB)
甲位二氢突厥酮(TMCHB)43052-87-5; 23726-94-5
(21)cis-beta-Damascone
乙位二氢突厥酮23726-92-3
(22)delta-Damascone
丁位突厥酮57378-68-4
(23)Dimethylbenzyl carbinyl acetate (DMBCA)
乙酸二甲基苄基原酯(DMBCA)151-05-3
(24)Hexadecanolactone
氧杂环十七烷-2-酮109-29-5
(25)Hexamethylindanopyran
佳乐麝香1222-05-5
(26)(DL)-Limonene
双戊烯138-86-3
(27)Linayl acetate
乙酸芳樟酯115-95-7
(28)Menthol
薄荷脑1490-04-6; 89-78-1;
2216-51-5
(29)Methyl salicylate
水杨酸甲酯119-36-8
(30)3-Methyl-5-(2,2,3-trimethyl-3-cyclopentelnyl)pent-4-en-2-ol
3-甲基-5-(2,2,3-三甲基-3-环戊烯-1-基)-4-戊烯-2-醇67801-20-1
(31)alpha-Pinene
α-蒎烯80-56-8
(32)beta-Pinene
β-蒎烯127-91-3
(33)Propylidene phthalide
3-丙亚基-1-异苯并呋喃酮17369-59-4
(34)Salicylaldehyde
水杨醛90-02-8
(35)alpha-Santalol
α-檀香醇115-71-9
(36)beta-Santalol
β-檀香醇77-42-9
(37)Sclareol
香紫苏醇515-03-7
(38)alpha-Terpineol
α-松油醇10482-56-1; 98-55-5
(39)Terpineol (mixture of isomers)
松油醇（异构体混合物）8000-41-7
(40)Terpinolene
萜品油烯586-62-9
(41)Tetramethyl acetyloctahydro naphthalenes
龙涎酮54464-57-2; 54464-59-4;
68155-66-8; 68155-67-9
(42)Trimethyl benzenepropanol (Majantol)
美研醇103694-68-4
(43)
Vanillin
香兰素121-33-5
(44)Cananga odorata and Ylang-ylang oil
衣兰油83863-30-3; 8006-81-3
(45)Cedrus atlantica bark oil
雪松油92201-55-3; 8000-27-9
(46)Cinnamomum cassia leaf oil
肉桂油8007-80-5
(47)Cinnamomum zeylanicum bark oil
锡兰肉桂树皮提取物84649-98-9
(48)Citrus aurantium amara flower oil
苦橙花油8016-38-4
(49)Citrus aurantium amara peel oil
酸橙提取物72968-50-4
(50)Citrus bergamia peel oil expressed
香柠檬果提取物89957-91-5
(51)Citrus limonum peel oil expressed
柠檬提取物84929-31-7
(52)Citrus sinensis (syn.: Aurantium dulcis) peel oil expressed
甜橙提取物97766-30-8; 8028-48-6
(53)Cymbopogon citratus / schoenanthus oils
香茅提取物89998-14-1; 8007-02-01;
89998-16-3
(54)Eucalyptus spp. leaf oil
桉叶油92502-70-0; 8000-48-4
(55)Eugenia caryophyllus leaf / flower oil
丁香油8000-34-8
(56)Jasminum grandiflorum / officinale
茉莉油84776-64-7; 90045-94-6;
8022-96-6
(57)Juniperus virginiana
柏木油8000-27-9; 85085-41-2
(58)Laurus nobilis fruit oil
月桂果油8007-48-5
(59)Laurus nobilis leaf oil
月桂叶油8002-41-3
(60)Laurus nobilis seed oil
月桂籽油84603-73-6
(61)Lavandula hybrida
杂薰衣草提取物91722-69-9
(62)Lavandula officinalis
薰衣草提取物84776-65-8
(63)Mentha piperita
辣薄荷叶提取物8006-90-4; 84082-70-2
(64)Mentha spicate
留兰香提取物84696-51-5
(65)Narcissus spp.
水仙提取物多种
(66)Pelargonium graveolens
香叶天竺葵提取物90082-51-2; 8000-46-2
(67)Pinus mugo
欧洲山松提取物90082-72-7
(68)Pinus pumila
偃松提取物97676-05-6
(69)Pogostemon cablin
广藿香油8014-09-03; 84238-39-1
(70)Rose flower oil (Rosa spp.)
玫瑰油多种
(71)Santalum album
檀香油84787-70-2; 8006-87-9
(72)Turpentine (oil)
松节油8006-64-2; 9005-90-7; 8052-14-0
二、提议禁用3种致敏香料
提议禁用的3种致敏香料是：
序号致敏香料名称CAS号
(56)Atranol (2,6-Dihydroxy-4-methyl-benzaldehyde)
地衣醇（2,6-二羟基-4-甲基苯甲醛）526-37-4
(57)Chloroatranol (3-Chloro-2,6-Dihydroxy-4-methyl-benzaldehyde)
氯冉醇57074-21-2
(58)Methyl heptine carbonate
2-辛炔酸甲酯111-12-6
2-辛炔酸甲酯（CAS号：111-12-6）是目前须进行标签的致敏香料。如果它成为禁用致敏香料，应将在原表格中除去。
一、对须进行标签的致敏香料清单的修订
根据玩具安全指令2009/48/EC附件II第III部分的现行要求，第11点的第3段中表格所列致敏香料，若在玩具或其部件中添加的浓度超过100 mg/kg，则应在玩具、加贴标签、包装或随附单页上注明该致敏香料的名称。
欧盟委员会提议对此清单进行如下修订：
1.香茅醇（CAS号：106-22-9），增加2个CAS号（1117-61-9和7540-51-4）；
2.增加61种致敏香料，详见下表：
序号致敏香料名称CAS号
(12)Acetylcedrene
甲基柏木酮32388-55-9
(13)Amyl salicylate
水杨酸戊酯2050-08-0
(14)trans-Anethole
反式茴香脑4180-23-8
(15)Benzaldehyde
苯甲醛100-52-7
(16)Camphor
樟脑76-22-2; 464-49-3
(17)Carvone
香芹酮99-49-0; 6485-40-1;
2244-16-8
(18)beta-Caryophyllene (ox.)
β-石竹烯87-44-5
(19)Rose ketone-4 (Damascenone)
大马酮23696-85-7
(20)alpha-Damascone (TMCHB)
甲位二氢突厥酮(TMCHB)43052-87-5; 23726-94-5
(21)cis-beta-Damascone
乙位二氢突厥酮23726-92-3
(22)delta-Damascone
丁位突厥酮57378-68-4
(23)Dimethylbenzyl carbinyl acetate (DMBCA)
乙酸二甲基苄基原酯(DMBCA)151-05-3
(24)Hexadecanolactone
氧杂环十七烷-2-酮109-29-5
(25)Hexamethylindanopyran
佳乐麝香1222-05-5
(26)(DL)-Limonene
双戊烯138-86-3
(27)Linayl acetate
乙酸芳樟酯115-95-7
(28)Menthol
薄荷脑1490-04-6; 89-78-1;
2216-51-5
(29)Methyl salicylate
水杨酸甲酯119-36-8
(30)3-Methyl-5-(2,2,3-trimethyl-3-cyclopentelnyl)pent-4-en-2-ol
3-甲基-5-(2,2,3-三甲基-3-环戊烯-1-基)-4-戊烯-2-醇67801-20-1
(31)alpha-Pinene
α-蒎烯80-56-8
(32)beta-Pinene
β-蒎烯127-91-3
(33)Propylidene phthalide
3-丙亚基-1-异苯并呋喃酮17369-59-4
(34)Salicylaldehyde
水杨醛90-02-8
(35)alpha-Santalol
α-檀香醇115-71-9
(36)beta-Santalol
β-檀香醇77-42-9
(37)Sclareol
香紫苏醇515-03-7
(38)alpha-Terpineol
α-松油醇10482-56-1; 98-55-5
(39)Terpineol (mixture of isomers)
松油醇（异构体混合物）8000-41-7
(40)Terpinolene
萜品油烯586-62-9
(41)Tetramethyl acetyloctahydro naphthalenes
龙涎酮54464-57-2; 54464-59-4;
68155-66-8; 68155-67-9
(42)Trimethyl benzenepropanol (Majantol)
美研醇103694-68-4
(43)
Vanillin
香兰素121-33-5
(44)Cananga odorata and Ylang-ylang oil
衣兰油83863-30-3; 8006-81-3
(45)Cedrus atlantica bark oil
雪松油92201-55-3; 8000-27-9
(46)Cinnamomum cassia leaf oil
肉桂油8007-80-5
(47)Cinnamomum zeylanicum bark oil
锡兰肉桂树皮提取物84649-98-9
(48)Citrus aurantium amara flower oil
苦橙花油8016-38-4
(49)Citrus aurantium amara peel oil
酸橙提取物72968-50-4
(50)Citrus bergamia peel oil expressed
香柠檬果提取物89957-91-5
(51)Citrus limonum peel oil expressed
柠檬提取物84929-31-7
(52)Citrus sinensis (syn.: Aurantium dulcis) peel oil expressed
甜橙提取物97766-30-8; 8028-48-6
(53)Cymbopogon citratus / schoenanthus oils
香茅提取物89998-14-1; 8007-02-01;
89998-16-3
(54)Eucalyptus spp. leaf oil
桉叶油92502-70-0; 8000-48-4
(55)Eugenia caryophyllus leaf / flower oil
丁香油8000-34-8
(56)Jasminum grandiflorum / officinale
茉莉油84776-64-7; 90045-94-6;
8022-96-6
(57)Juniperus virginiana
柏木油8000-27-9; 85085-41-2
(58)Laurus nobilis fruit oil
月桂果油8007-48-5
(59)Laurus nobilis leaf oil
月桂叶油8002-41-3
(60)Laurus nobilis seed oil
月桂籽油84603-73-6
(61)Lavandula hybrida
杂薰衣草提取物91722-69-9
(62)Lavandula officinalis
薰衣草提取物84776-65-8
(63)Mentha piperita
辣薄荷叶提取物8006-90-4; 84082-70-2
(64)Mentha spicate
留兰香提取物84696-51-5
(65)Narcissus spp.
水仙提取物多种
(66)Pelargonium graveolens
香叶天竺葵提取物90082-51-2; 8000-46-2
(67)Pinus mugo
欧洲山松提取物90082-72-7
(68)Pinus pumila
偃松提取物97676-05-6
(69)Pogostemon cablin
广藿香油8014-09-03; 84238-39-1
(70)Rose flower oil (Rosa spp.)
玫瑰油多种
(71)Santalum album
檀香油84787-70-2; 8006-87-9
(72)Turpentine (oil)
松节油8006-64-2; 9005-90-7; 8052-14-0
二、提议禁用3种致敏香料
提议禁用的3种致敏香料是：
序号致敏香料名称CAS号
(56)Atranol (2,6-Dihydroxy-4-methyl-benzaldehyde)
地衣醇（2,6-二羟基-4-甲基苯甲醛）526-37-4
(57)Chloroatranol (3-Chloro-2,6-Dihydroxy-4-methyl-benzaldehyde)
氯冉醇57074-21-2
(58)Methyl heptine carbonate
2-辛炔酸甲酯111-12-6
2-辛炔酸甲酯（CAS号：111-12-6）是目前须进行标签的致敏香料。如果它成为禁用致敏香料，应将在原表格中除去。
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